extraction - spectrophotometric determination of palladium with tetrabutyl ammonium iodide

Extraction - Spectrophotometric Determination of Palladium with Tetrabutyl Ammonium Iodide

A sensitive and selective extraction - spectrophotometric method for the determination of trace amounts of palladium is reported. The method is based on quantitative extraction of brownish tetrabutylammoium tetraiodopalladium (II) ion pair into a small valume of chloroform at pH 1.3-12.0, followed by spectrophotometric measurements. The Beer's law is obeyed over the range 0.02-1.09 <em...

Spectrophotometric determination of palladium by extraction of its

A new method is proposed for naphthalene extraction and spectrophotometric determination of palladium at the ppm level with chinoform. The method is based on the formation of a yellow complex which is extractable by molten naphthalene and on the dissolution of the extract in dioxane. The yellow solution follows Beer's law at 462 nm over ~he range of 7 to 140 ~g of palladium per 10 ml of dioxane...

EXTRACTION-SPECTROPHOTOMETRIC DETERMINATION OF AMMONIUM ION BY DIBENZO- 18-CROWN-6 AND CALMAGITE

An extraction-spectrophotometric method for the determination of trace amounts of ammonium ion is described. Ammonium ion is effectively extracted as a neutral ternary complex NH . DB 18C6. calmagite at pH 3.0 into chloroform, followed by spectrophotometric determination at =48 5 nm. Molar absorptivity of the ternary complex at this wavelength is 1.08 10 mol cm . Beer's law is obeyed over...

Spectrophotometric determination of uric acid based on fading of o-hydroxyhydroquinonephthalein-palladium(II)-hexadecyltrimethyl-ammonium complex.

A simple and highly sensitive spectrophotometric method for the determination of uric acid (UA) was established based on fading of the o-hydroxyhydroquinonephthalein-palladium(II)-hexadecyltrimethylammonium complex. In the determination of UA, Beer's law is obeyed in the range of 0.01-0.20 microg ml(-1), with an effective molar absorptivity at 635 nm, the relative standard deviation being 6.5 x...

Extraction - Spectrophotometric Determination of Nic and Palladium ( II ) with 0 , 0 p - Diethyldithiophosphate 1 kel ( II )

Nickel(II) of 0.04-1.4 mmol dm-3 and palladium(II) of 1-32 μmol dm-3 were extracted quantitatively into chloroform from the aqueous phases containing 0.2 mol dm-3 and 2 mmol dm-3 0,0'-diethyldithiophosphate(dtp-) at pH 1-7 and 1-13, and determined at 385 nm (c=8.4x 102 mol-' dm3 cm-') and 298 nm (e=2.9x 104 mol-' dm3 cm-'), respectively. The determination of nickel was affected with many divers...

Selective extraction spectrophotometric determination